By A.W. Parkins
This booklet offers an built-in view of the organometallic chemistry of transition and non-transition components. Early chapters take care of the elemental ideas, instruction and constitution of organometallic compounds. next chapters talk about the reactivity of those compounds and the purposes of organometallic compounds as stoichiometric reagents and catalysts. The textual content is comprehensively referenced all through and can also be a advisor to organometallic literature, expanding its usefulness to all these enthusiastic about the learn or educating of this more and more very important department of undergraduate chemistry.
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Additional resources for An Introduction to Organometallic Chemistry
33) Even when an alkyl group does not contain ~-hydrogen atoms, complications may arise from reactions of the a-hydrogen atoms. 147. Another problem which can arise when transition metal halides react with organometallic reagents is that they may be reduced, often to the metal. 34). 35), M = Fe; Kealy and Pauson, 1951). 1 2CsHsMgBr + MCl 3 • (M = Fe, Cr, V) (71 s . 35). , 1966). 37); Wittig and Hellwinkel, 1964). 38); Kramer and Brown, 1974). 38) These reactions are conveniently carried out in pentane and the soluble product removed by decantation from the insoluble lithium methoxide.
Chem. 73,1 Krief, A. (1980). Tetrahedron 36, 2596 Langer, A. W. ) (1974). Polyamine-chelated Alkali Metal Compounds, Advances in Chemistry Series, no. 130. C. Larock, R. C. (1976). J. organomet. Chem. Library 1,257 Lehmkuhl, H. (1973). Synthesis, 377 Lindley, P. , and Woodward, P. J. chem. Soc. (Aj 123 Luijten, J. G. , and van der Kerk, G. J. M. (1964). Rec. Trav. Chim. , and Shaw, B. L. (1976). J. chem. Soc. chem. Commun. 292 Mengoli, G. (1979). Rev. Silicon, Germanium, Tin Lead Compounds 4, 59 Moser, G.
CH3 'CI~ 'CH 3 AI'\ 'I, Al VIII VII CH3 , CH/·...... ' H" III Al ........ CH 3 'CH 3 IX bridging groups are present. The x-ray structure of AhMe6 has been determined at low temperature and this allowed the hydrogen atoms on the bridging methyl groups to be located (X; Huffman and Streib, 1971). The study revealed that these hydrogen atoms are not involved in direct interaction with the aluminium atoms. Although the bonding in B2 H6 and Al2 Me6 is similar in principle, there are differences.
An Introduction to Organometallic Chemistry by A.W. Parkins