By Hisashi Yamamoto, Kazuaki Ishihara
This two-volume set covers all new advancements and, moreover, contains the recent thought of mixed Bronsted and Lewis acid catalysis, constructed through Hisashi Yamamoto himself. the wonderful editorial workforce has prepare an both best staff of professional authors, leading to a real treasure trove of crucial info -- making this a needs to for each chemist operating in natural chemistry and catalysis, in academia in addition to in undefined.
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Additional info for Acid Catalysis in Modern Organic Synthesis, vol 2
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1 1 . 4 Protection of the Amino G roup Cyclic N ,O-aminals can be chemoselectively cleaved in the presence of O,O-acetals using a catalytic amount of BiBr3 in acetonitrile (Equation 46) [1 14]. Other amine protective groups as well as MOM, Cbz, Ac, protecting groups for hydroxyl functions are stable under these conditions. It is noteworthy that the reaction rates could be accelerated by adding a catalytic amount of water revealing again the B LA behavior of such bismuth catalysis. The same observation has been made in the BiCb mediated chemoselective deprcitection of N-Boc groups in amino acids and peptides [ 1 1 5 ] .
Acid Catalysis in Modern Organic Synthesis, vol 2 by Hisashi Yamamoto, Kazuaki Ishihara